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Photochemistry on Venus: a very fast evolution

1 September 2012

A team of astronomers of the Paris Observatory has just highlighted a very rapid variation of the sulphur dioxide (SO2) on the surface of Venus). Mapping of Venus was made in the infrared with the NASA telescope IRTF and with the spectro-imager TEXES in January 2012. It has highlighted of very strong variations of SO2 on 24 hours time scale, while there is no change in the map of water (H2O). The reason is probably related to the very short photochemical life of SO2 compared with that of H2O. This discovery will help a better understanding of the photochemistry and dynamics of the atmosphere of Venus, still poorly understood. The data are very complementary to those of Venus Express.

Planet Venus, permanently covered with a thick cloud deck of sulfuric acid, exhibits a complex atmospheric circulation and strong photochemical activity, with processes — like the sulfur cycle - which are not fully understood presently. Since 2006, the Venus Express spacecraft, in orbit around the planet, monitors its atmosphere, its circulation and photochemistry in order to bring answers to these questions. In parallel, ground-based observations of the Venus disk, at specific wavelengths characteristic of various atmospheric species, can bring complementary information.

Figure 1: Maps of the HDO abundance at the cloud level, obtained from the line depth ratio of two weak neighbouring lines of HDO and CO2. Left: 10 January 2012; Right: 12 January 2012. Assuming a D/H ratio of 200 times the terrestrial value (as measured by Venus Express), the mean mixing ratio of water is 1.5 10-6, in agreement with Venus Express measurements. Click on the image to enlarge it

In January 2012, infrared observations of Venus were recorded with the TEXES imaging spectrometer (Texas Echelon cross-Echelle Spectrograph) at the NASA IRTF (InfraRed Telescope Facility) at Mauna Kea Observatory (Hawaii). The spectra recorded at 7.3-7.4 mm with a resolving power of 80000 probe the atmosphere of Venus at the level of the cloudtop. Maps of the water vapor abundance (measured through its proxy HDO) and the sulfur dioxyde SO2 have been measured during three successive nights. The abundances are measured from the line depth ratio of HDO and SO2 versus CO2, the major atmospheric component. H2O and SO2 are the two key elements involved in the condensation and saturation of the sulfuric acid present in the clouds. Surprisingly, the maps of the two components show spectacular differences. While the H2O map (Fig. 1), globally uniform, shows little variation on a timescale of 48 hours, the SO2 map (Fig. 2) shows local variations up to a factor 10 and very strong temporal variations on a timescale of 24 hours. These variations cannot be due to dynamical motions as they would imply very fast winds at the cloud level, not compatible with the wind speeds measured by Venus Express. More likely, the SO2 variations are due to the very short photochemical lifetime of sulfur dioxyde. Below the clouds, the atmosphere of Venus is strongly convective. Small SO2 convective cells, formed at the cloud level, could disappear in less than a day and be responsible for the observed maps.

Figure 2: Maps of the SO2 abundance on Venus at the cloud level during three consecutive nights (January 10, 11 and 12, 2012), obtained from the line depth ratio of two weak neighbouring lines of SO2 and CO2. The maximum mixing ratio of SO2 varies from 75 10-9 (Jan. 10) to 125 10-9 (Jan. 11) with an intermediate value on Jan. 12. These values are compatible with Venus Express results. Click on the image to enlarge it